1) UFO: Enemy Unknown (you should try OpenXcom)
2) XCOM: Apocalypse (you should try OpenApoc)
3) Fallout
4) Elder Scrolls: Daggerfall (you should try Daggerfall Unity)
5) Commander Keen: Goodbye Galaxy
Yes, Fallout was released for DOS. I have played it in DOSBox many times.
Diablo was not released for DOS.
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